The article gives characteristics of the current state of the Ukrainian scientific educational libraries network’s digital resources, presenting the results of the websites’ content analysis. It determines the features of the full-text resources’ thematic and type-specific structure of the leading sectorial electronic libraries as well clarifies the factors reducing the digitalization efficiency of the educational libraries of Ukraine network, develops a corporate cooperation strategy as to formation of consolidated and conveniently structured pedagogical science and education digital resource, equipped with convenient search services.